Very shallow junctions for S/D extension in deep sub-micron CMOS devices are required to suppress the short channel effect as devices scaling down, and the surface concentrations (Ns) of these junctions need to be kept in a higher value to reduce the series resistance of the lightly doped drain structure. But it is very difficult for the conventional ion implantation to meet the requirements above. This article presents the results of forming very shallow and ultrashallow junctions used in 0.25 micron and 0.10 micron CMOS devices respectively with low energy implantation (LEI) and pre-amorphization implantation plus low energy implantation (PAI+LEI). The LEI was performed on the modified normal ion-implantor (IM-200 M). Using LEI only the minimum junction depth, is 61 nm for NMOS and 57 nm for PMOS (nsub=1×1018 cm-3) respectively after 1000°C RTA and both Ns are above 3×1019 cm-3. While using Ge PAI+LEI, under the optimized processing condition, the junction depth of 58 nm for NMOS and 42 nm for PMOS are obtained, with the leakage current density being 4 nA/cm2.