THERMODYNAMIC PROPERTIES AND COMPOUND CLUSTER FORMATION IN LIQUID ZINC-ANTIMONY ALLOYS.

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作者：
Rubin, Ivan B.
Komarek, Kurt L.
Miller, Edward
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Zeitschrift fuer Metallkunde/Materials Research and Advanced Techniques | 1974年 / 65卷 / 03期
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Activities of zinc in liquid Zn-Sb alloys containing 10 to 90 at. % Zn were determined by the emf method between the liquidus temperature and 660 degree C. Strongly temperature dependent anomalies observed in the thermodynamic functions are explained by the existence of Zn//4Sb//3 compound clusters in the melt. With increasing temperature the clusters dissociate and the anomalies disappear. The effects of compound cluster formation in liquid alloys on thermodynamic properties are discussed.
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页码：191 / 199
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