Infrared reflectance spectra have been measured on typical charge-transfer complex crystals, TTF-chloranil, M//2P-TCNQF//4 and Alkali(K,Rb)-TCNQ. Each of these crystals undergoes characteristic phase transition accompanied by dimeric distortions. From the analysis of observed polarized reflection spectra, characteristic behaviour of lattice distortion near the respective phase transition temperatures are investigated.