15N NMR spectra of cobalt(III) complexes containing 15NO2-

被引：0

作者：

Odaka, Yoshio ^{[1
]}

Yamasaki, Akira ^{[1
]}

Watabe, Masatoshi ^{[1
]}

机构：

[1] General Education Department, Kogakuin University, Hachioji, Tokyo,192, Japan

来源：

Bulletin of the Chemical Society of Japan | 1985年 / 58卷 / 11期

关键词：

Coordination reactions - Cobalt compounds - Nuclear magnetic resonance;

D O I：

暂无

中图分类号：

O6 [化学]; TQ03 [化学反应过程]; TQ02 [化工过程（物理过程及物理化学过程）];

学科分类号：

0703 ; 081701 ; 081704 ;

摘要：

Synopsis. The nitrogen-15 nuclear magnetic resonance spectra of the cobalt(III) complexes containing 15NO2- were first measured; the coordination chemical shifts, Δδ (=δcomplex-δfree), were found to be from 135.0 to 161.5 ppm. The relationship between Δδ and the geometrical configuration was discussed in terms of the paramagnetic anisotropy of the cobalt(III) ion. © 1985 The Chemical Society of Japan.

引用

页码：3407 / 3408

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