1,3,5-tri-tert-butyl-5-(1,3,5-tri-tert-butyl-4-oxo-2, 5-cyclohexadienyl)methylbicyclo-[4.1.0]hept-3-en-2-one, a highly hindered propane

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作者
Rieker, Anton [1 ]
Neumayer, Markus [1 ]
Hiller, Wolfgang [1 ]
机构
[1] Universitaet Tuebingen, Tuebingen, Germany
关键词
Addition reactions - Aromatic hydrocarbons - Conformations - Crystal atomic structure - Deuterium - Nuclear magnetic resonance spectroscopy;
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摘要
The title compound, C38H62O2, is one of the reaction products of diazomethane with two equivalents of 2,4,6-tri-tert-butylphenoxyl. In the crystal structure, the cyclo-propane ring is almost perpendicular to the basal plane of the boat-configured cyclohexenone ring.
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页码:2351 / 2353
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