Neutral bis(ethylenedithio)tetrathiafulvalene at 100 K

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作者：
Guionneau, Philippe
Chasseau, Daniel
Howard, Judith A.K.
Day, Peter
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来源：
Acta Crystallographica, Section C: Crystal Structure Communications | 2000年 / 56卷 / 04期
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D O I：
10.1107/S0108768199016754
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摘要：
The low-temperature crystal structure of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF), C10H8S8, is similar to its high-temperature structure. The room-temperature central bond lengths of this molecule are often used as reference in empirical methods to estimate the charge carried by the (BEDT-TTF)xn+ cations in the BEDT-TTF molecule-based organic conductors. We show that the method we previously reported can still be used with low-temperature BEDT-TTF salts data. Moreover, we confirm the purely thermal origin of the ordering of the ethylene group.
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页码：453 / 454
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