The temperature relations of electrical conductivity, structure, and chemical composition of GdFe//2 films of varying thickness produced in different modes of discharge with oscillating electrons are investigated. It is shown that the crystallization process is a function of the thickness of the film and not the discharge mode. An hysteresis path of the temperature relation of the electrical conductivity is detected and explained. Data from chemical analysis show that the crystallized films of GdFe//2 are resistant to the effect of air.