Chemistry and Technology of organotin Compounds - 9. To the Progress of the Modified Wurtz-reaction to n-Butyltin Compounds.

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作者
Thust, Ulf
Tzschach, Alfred
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来源
Chemische Technik (Leipzig) | 1981年 / 33卷 / 03期
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CHEMICAL REACTIONS - Reaction Kinetics - ORGANIC COMPOUNDS - Chemistry - SODIUM COMPOUNDS - SOLVENTS - Chemistry;
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摘要
This paper describes a modified Wurtz-reaction in which n-butyltin compounds are synthesied with the use of solid sodium as diffusion-controlling agent. Reaction numbers have been determined experimentally and reaction mechanism is proposed as function of reaction parameters. This method can also be used for synthesis of octylin compounds as well as of phenylenetin compounds.
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页码:143 / 144
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