Chemistry and Technology of organotin Compounds - 9. To the Progress of the Modified Wurtz-reaction to n-Butyltin Compounds.

被引：0

作者：

Thust, Ulf

Tzschach, Alfred

机构：

来源：

Chemische Technik (Leipzig) | 1981年 / 33卷 / 03期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - ORGANIC COMPOUNDS - Chemistry - SODIUM COMPOUNDS - SOLVENTS - Chemistry;

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摘要：

This paper describes a modified Wurtz-reaction in which n-butyltin compounds are synthesied with the use of solid sodium as diffusion-controlling agent. Reaction numbers have been determined experimentally and reaction mechanism is proposed as function of reaction parameters. This method can also be used for synthesis of octylin compounds as well as of phenylenetin compounds.

引用

页码：143 / 144

共 26 条

[1] CHEMISTRY AND TECHNOLOGY OF ORGANOTIN COMPOUNDS .9. TO THE PROGRESS OF THE MODIFIED WURTZ-REACTION TO NORMAL-BUTYLTIN COMPOUNDS
THUST, U
TZSCHACH, A
CHEMISCHE TECHNIK, 1981, 33 (03): : 143 - 144
[2] CHEMISTRY OF CUMMULATED DOUBLE BOND COMPOUNDS .9. REACTION OF SULFURDIIMIDES WITH DIPHENYLKETENE
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[3] CHEMISTRY OF EPOXY COMPOUNDS .9. EPOXIDATION OF OLEAMIDE AND N-SUBSTITUTED OLEAMIDES WITH PERACETIC ACID
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[4] POLYHALO-ORGANOMETALLIC AND -ORGANOMETALLOIDAL COMPOUNDS .9. REACTION OF N-BUTYLLITHIUM WITH (PENTAFLUOROPHENYL)TRIMETHYLSILANE
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[5] CYANATE COMPOUNDS AND THEIR REACTIVITY .9. REACTION BEHAVIOR OF VANADIUM(III) THIOCYANATE TOWARD PYRIDINE-N-OXIDES
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[6] STUDIES IN COORDINATION CHEMISTRY .9. INVESTIGATION OF STEREOCHEMISTRY OF SOME COMPLEX COMPOUNDS OF COBALT(II) WITH N-SUBSTITUTED SALICYLALDIMINES
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[7] CHEMISTRY OF HETEROCYCLIC N-OXIDES AND RELATED COMPOUNDS .9. DEHYDRATION OF HANTCH ESTER BY NITROOXY AND CARBETHOXY DERIVATIVES OF PYRIDINE N-OXIDE
KURBATOVA, AS
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NIYAZOVA, DA
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1977, (12): : 1651 - 1653
[8] The chemistry of N,N-bis(siloxy)enamines, part 9.: A general method for the preparation of α-hydroxy oximes from aliphatic nitro compounds
Tabolin, AA
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SYNTHESIS-STUTTGART, 2005, (10): : 1656 - 1662
[9] REACTIONS OF ALPHA-OXIDES WITH ALKYLTINACYLATES .9. DEPENDENCE OF THE REACTION-RATE OF GLYCIDYL ETHERS WITH BENZOATES AND ALKYL(ARYL)TIN HALIDES ON THE STRUCTURE OF ORGANOTIN COMPOUNDS
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[10] ELECTRON CHEMICAL SYNTHESES OF N-HETEROCYCLES .9. REACTION OF ANODICALLY-GENERATED DIAZENIUM IONS WITH ENOLIZABLE CARBONYL-COMPOUNDS
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