Kinetics and mechanism of the reaction of alkaline hydrolysis of Reumicin

被引：0

作者：

Shorshnev, S.V. ^{[1
]}

Chernyshev, A.I. ^{[1
]}

Esipov, S.E. ^{[1
]}

机构：

[1] All-Union Scientific-Research Inst, of Antibiotics, Russia

来源：

Kinetics and Catalysis | 1988年 / 29卷 / 1 pt 1期

关键词：

Chemical Reactions - Reaction Kinetics;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The kinetics of alkaline hydrolysis of the antibiotic Reumicin were investigated by 1H NMR spectroscopy. The mechanism of the reaction was proposed, which includes the reversible formation of the adduct of Reumicin with the hydroxyl ion and the subsequent transformation of the intermediate into the final product: the 6-(3-methyl-ureido)-1,2,4-triazine-5-carboxylic acid anion. The kinetic scheme satisfies the experimental data.

引用

页码：57 / 60

共 5 条

[1] MODELING OF ENZYME REACTION KINETICS.
Cheruy, A.
American Society of Mechanical Engineers (Paper), 1976, (76 -Aut-EE):
[2] KINETICS OF ACID-HYDROLYSIS OF PHASE-TRANSFERRED TETRAALKYLAMMONIUM THIOCYANATES
HAMARAT, Y
REUBEN, BG
SOLVENT EXTRACTION AND ION EXCHANGE, 1988, 6 (02) : 375 - 380
[3] Mechanism and Kinetics of Cement Stone Hardening.
Polak, A.F.
Ratinov, V.B.
1600,
[4] KINETICS AND MECHANISM OF HIGH-TEMPERATURE PHOSPHIDATION OF VANADIUM
SASAKI, Y
YAMAZAKI, T
SHIMADA, A
JOURNAL OF THE JAPAN INSTITUTE OF METALS, 1986, 50 (02) : 181 - 185
[5] Kinetics of the Reaction Between Germanium and a Solution of Bromine in Germanium Tetrabromide.
Eliseev, V.M.
Repinskii, S.M.
Sveshnikov, L.L.
Neorganiceskie materialy, 1981, 17 (09): : 1529 - 1532

← 1 →