Promotion of 110 K superconducting phase in the Bi(Pb)-Sr-Ca-Cu-O system

被引:0
作者
Lu, S.W. [1 ]
Lee, W.H. [1 ]
Wu, P.T. [1 ]
机构
[1] Industrial Technology Research Inst, Taiwan
来源
MRL bulletin of research and development | 1990年 / 4卷 / 01期
关键词
Bismuth Compounds - Phase Transitions - Ceramic Materials - Magnetization - X-Rays - Diffraction;
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摘要
An unmixed 110 K phase of the Bi(Pb)-Sr-Ca-Cu-O superconductor was synthesized by annealing the sample with the nominal composition (Bi0.85Pb0.15)2 (Ca0.65Sr0.35)4.25Cu4.75Oy at 845°C for 50 hours. X-ray diffraction patterns indicate that the sample is basically equivalent to the so-called 2223 BSCCO phase. Magnetization data show a single superconducting transition of 110 K. With suitable amounts of Pb plus excess Ca and Cu instead of the ideal Bi2Sr2Ca2Cu3Oy, the 80 K or 2212 superconducting phase can be significantly decreased.
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页码:43 / 46
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