Stability of (C6H5C2H4NH3)2Pb(BrxI4-x) mixed crystals

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Natl Defense Acad, Kanagawa, Japan ^{[1
]}

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Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers | 1997年 / 36卷 / 11期

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摘要：

The stability of (C6H5C2H4NH3)2Pb(BrxI4-x) mixed crystals was investigated and the degradation process was discussed. A thin film of microcrystalline (RNH3)2PbBr4 was more stable than that of (RNH3)2PbI4, and the stability of (C6H5C2H4NH3)2Pb(BrxI4-x) mixed crystals was improved by the replacement of I with Br. X-ray diffraction and optical absorption measurements suggested that the (RNH3)2PbI4 crystal changed to β-phenethylamine (C6H5C2H4NH2) coordinated PbI2 with the elapse of time. In order to determine the origin of degradation, a light irradiation-induced degradation effect was also studied. The photochemical reaction was one of the possible reasons for degradation.

引用

页码：6876 / 6879

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[41] Synthesis and crystal sructure of a new dihydrogenomonophosphate (4-C2H5C6H4NH3)H2PO4 [J].

Kaabi, K ;

Rayes, A ;

Ben Nasr, C ;

Rzaigui, M ;

Lefebvre, F .

MATERIALS RESEARCH BULLETIN, 2003, 38 (05) :741-747

[42] SynthesesandCharacterizationsof（4-NH2C6H4S）4Snand（4-NH2C6H4S）2（4-NH3C6H4S）2Sn]Cl2 [J].

WANG LongSheng ZHANG JianJun DU WenXin HU ShengMin FU RuiBiao XIA ShengQing WU XinTao XIANG ShengChang LI YaMin FU ZhiYong State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China .

结构化学, 2005, (01) :79-83

[43] Pressure-Induced Broadband Emission of 2D Organic-Inorganic Hybrid Perovskite (C6H5C2H4NH3)2PbBr4 [J].

Zhang, Long ;

Wu, Lianwei ;

Wang, Kai ;

Zou, Bo .

ADVANCED SCIENCE, 2019, 6 (02)

[44] Coupling of Magnetic and Elastic Domains in the Organic-Inorganic Layered Perovskite-Like (C6H5C2H4NH3)2FeIICl4 Crystal [J].

Nakayama, Yuki ;

Nishihara, Sadafumi ;

Inoue, Katsuya ;

Suzuki, Takashi ;

Kurmoo, Mohamedally .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (32) :9367-9370

[45] LATTICE STABILITY IN A2MCL6 IONIC-CRYSTALS (A=C5H5NH OR CH3C5H4NH - M=SN OR TE) [J].

HORIUCHI, K ;

IWAFUNE, H ;

ASAJI, T ;

NAKAMURA, D .

JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 (43) :9075-9078

[46] ENTHALPIES OF FORMATION OF TI(ETA-C5H5)2(OR)2 COMPLEXES (R=C6H5, 2-CH3C6H4, 3-CH3C6H4, 4-CH3C6H4, AND 2-CLC6H4) [J].

DIAS, AR ;

SALEMA, MS ;

SIMOES, JAM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 222 (01) :69-78

[47] Syntheses and Characterizations of (4-NH2C6H4S)4Sn and [(4-NH2C6H4S)2(4-NH3C6H4S)2Sn]Cl2 [J].

Wang, LS ;

Zhang, HJ ;

Du, WX ;

Hu, SM ;

Fu, RB ;

Xia, SQ ;

Wu, XT ;

Xiang, SC ;

Li, YM ;

Fu, ZY .

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (01) :79-83

[48] Syntheses and Characterizations of （4-NH2C6H4S）4Sn and （4-NH2C6H4S）2（4-NH3C6H4S）2Sn]Cl2 [J].

WANG Long-Sheng ZHANG Jian-Jun DU Wen-Xin HU Sheng-Min FU Rui-Biao XIA Sheng-Qing WU Xin-Tao XIANG Sheng-Chang LI Ya-Min FU Zhi-Yong (State Key Laboratory of Structural Chemistry .

Chinese Journal of Structural Chemistry, 2005, (01) :79-83

[49] Structure and properties of [2-NH2C5H4NH][SbCl4] and [2-NH2C5H4NH][SbBr4] [J].

Kulicka, B ;

Jakubas, R ;

Bator, G ;

Ciunik, Z ;

Medycki, W .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2004, 16 (46) :8155-8172

[50] PHYSICOCHEMICAL CHARACTERIZATION OF FERROELASTIC CRYSTALS (C2H5NH3)2HGCL4 AND (C3H7NH3)2HGCL4 [J].

BENSALAH, A ;

DAOUD, A ;

MIANE, JL ;

RAVEZ, J ;

HAGENMULLER, P .

REVUE DE CHIMIE MINERALE, 1984, 21 (06) :795-803

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