Behavior of diglycerides and conjugated fatty acid triglycerides in reverse-phase chromatography

被引：0

作者：

Chang, M.-K. ^{[1
]}

Conkerton, E.J. ^{[1
]}

Chapital, D. ^{[1
]}

Wan, P.J. ^{[1
]}

机构：

[1] USDA, New Orleans, United States

来源：

JAOCS, Journal of the American Oil Chemists' Society | 1994年 / 71卷 / 10期

关键词：

Fatty acids - High performance liquid chromatography - Lipids - Molecular structure - Separation;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The behavior of conjugated fatty acid triglycerides and diglycerides on reverse-phase chromatography was studied. Trieleostearin is a geometric isomer of trilinolenin. The conjugated double bond arrangement in trieleostearin enhances its hydrophobic interaction with the stationary phase and causes it to be eluted later than trilinolenin. In separation of `critical pain' of tri- and diglycerides, diglycerides elute later than triglycerides due to the longer fatty acid constituent. Position isomers of 1,2- and 1,3-diglycerides can be separated by reverse-phase high-performance liquid chromatography.

引用

页码：1173 / 1175