Magnetic and vibronic interactions in mixed-valence clusters: a general approach based on the angular momentum theory

被引:0
|
作者
Borras-Almenar, J.J. [1 ]
Clemente, J.M. [1 ]
Coronado, E. [1 ]
Georges, R. [1 ]
Kishinevsky, H. [1 ]
Klokishner, S.I. [1 ]
Ostrovskii, S.M. [1 ]
Palii, A.V. [1 ]
Tsukerblat, B.S. [1 ]
机构
[1] Universidad de Valencia, Burjasot, Spain
来源
Journal of Magnetism and Magnetic Materials | 1995年 / 140-144卷 / pt 3期
关键词
Electrons - Ions - Mathematical operators - Matrix algebra - Problem solving - Quantum theory - Transition metals;
D O I
暂无
中图分类号
学科分类号
摘要
A general solution of the double exchange problem is given for a mixed-valence system in which one migrating electron or hole is delocalized over an arbitrary number of transition metal ions (spin-core). A new efficient way for solving the magnetic vibronic problem is suggested based on the semiclassical approach.
引用
收藏
页码:1807 / 1808
相关论文
共 50 条
  • [41] ELECTRON-TRANSFER IN TETRANUCLEAR MIXED-VALENCE IRON CLUSTERS - ROLE OF THE TOPOLOGY ON THE MAGNETIC-PROPERTIES
    BORRASALMENAR, JJ
    CORONADO, E
    GEORGES, R
    GOMEZGARCIA, CJ
    CHEMICAL PHYSICS, 1992, 166 (1-2) : 139 - 144
  • [42] Magnetic properties and tunnel exchange states of dimeric mixed-valence clusters with two-electron transfer
    Koropchanu, VP
    Paladii, FG
    Gamurar, VY
    JOURNAL OF STRUCTURAL CHEMISTRY, 1997, 38 (06) : 871 - 877
  • [43] DOUBLE EXCHANGE IN TETRAMERIC MIXED-VALENCE CLUSTERS - MAGNETIC-PROPERTIES, ELECTRONIC HEAT-CAPACITY
    BELINSKII, MI
    TSUKERBLAT, BS
    ZAITSEV, SA
    BELINSKAYA, IS
    NEW JOURNAL OF CHEMISTRY, 1992, 16 (07) : 791 - 799
  • [44] New alkoxo-bridged mixed-valence cobalt clusters: Synthesis, crystal structures and magnetic properties
    Tudor, Violeta
    Marin, Geanina
    Lloret, Francesc
    Kravtsov, Victor Ch.
    Simonov, Yurii A.
    Julve, Miguel
    Andruh, Marius
    INORGANICA CHIMICA ACTA, 2008, 361 (12-13) : 3446 - 3452
  • [45] Magnetic properties and tunnel exchange states of dimeric mixed-valence clusters with two-electron transfer
    V. P. Koropchanu
    F. G. Paladii
    V. Ya. Gamurar
    Journal of Structural Chemistry, 1997, 38 : 871 - 877
  • [46] Self-assembly, structures, magnetic properties and solution behaviors of six mixed-valence cobalt clusters
    Li, Yun-Wu
    Guo, Ling-Yu
    Feng, Lei
    Jaglicic, Zvonko
    Zeng, Su-Yuan
    Sun, Di
    CRYSTENGCOMM, 2017, 19 (39): : 5897 - 5906
  • [47] METAL TO METAL INTERACTIONS IN WEAKLY COUPLED MIXED-VALENCE COMPLEXES BASED ON RUTHENIUM AMMINES
    SUTTON, JE
    TAUBE, H
    INORGANIC CHEMISTRY, 1981, 20 (10) : 3126 - 3134
  • [48] Effect of magnetic exchange, double exchange, vibronic coupling, and asymmetry on magnetic properties in d2-d3 mixed-valence dimers
    Yang, XH
    Hu, HQ
    Chen, Z
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2005, 103 (02) : 190 - 197
  • [49] MAGNETIC MIXED-VALENCE D(2)-D(1)-D(1) TRIMERS WITH PARTIAL ELECTRON DELOCALIZATION - VIBRONIC COUPLING AND MAGNETIC-PROPERTIES
    BORRASALMENAR, JJ
    CORONADO, E
    TSUKERBLAT, BS
    CHEMICAL PHYSICS, 1993, 177 (01) : 1 - 14
  • [50] TEMPERATURE-DEPENDENT MAGNETIC EXCHANGE INTERACTIONS IN A MIXED-VALENCE COMPLEX - A NEUTRON-SCATTERING STUDY
    WHITE, RP
    ALBASSEET, JO
    CANNON, RD
    KEARLEY, GJ
    JAYASOORIYA, UA
    PHYSICA B, 1989, 156 : 367 - 369