Semicontinuous emulsion polymerization of methyl methacrylate, ethyl acrylate, and methacrylic acid

被引：0
|
作者：
Amalvy, J.I. [1 ]
机构：
[1] CIDEPINT, La Plata, Argentina
来源：
| 1996年 / John Wiley & Sons Inc, New York, NY, United States卷 / 59期
关键词：
Ethyl acrylate - Methacrylic acid - Methyl methacrylate;
D O I：
10.1002/(SICI)1097-4628(19960110)59:23.0.CO;2-R
中图分类号：
学科分类号：
摘要：
By a semicontinuous emulsion polymerization method with a variable monomer feed rate, a terpolymeric latex of methyl methacrylate and ethyl acrylate functionalized with methacrylic acid was synthesized. Conversion and reactor temperature vs. time were followed during the reaction. Characterization of the latex system was performed by particle-size measurements, scanning electron microscopy, infrared spectroscopy, viscometric molecular weight, glass transition temperature measurement, and rheological behavior.
引用
收藏
相关论文
共 50 条
  • [31] Preparation of titanium dioxide/poly(methyl methacrylate-co-n-butyl acrylate-co-methacrylic acid) hybrid composite particles via emulsion polymerization
    Yu, DG
    An, JH
    Bae, JY
    Ahn, SD
    Kang, SY
    Suh, KS
    JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 97 (01) : 72 - 79
  • [32] INFLUENCE OF INHIBITING ADDITIVES ON EMULSION (CO)POLYMERIZATION OF BUTYL ACRYLATE AND METHACRYLIC-ACID
    KULIKOV, SA
    YABLOKOVA, NV
    ALEKSANDROV, YA
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1991, 33 (04): : 749 - 754
  • [33] Study on concentrated emulsion polymerization of methyl methacrylate/butyl acrylate initiated by redox system
    Zhang, HT
    Wang, AL
    Cao, JH
    ACTA POLYMERICA SINICA, 2003, (01) : 23 - 29
  • [34] GAMMA-RADIATION-INITIATED EMULSION POLYMERIZATION OF BUTYL ACRYLATE AND OF METHYL-METHACRYLATE
    ONEILL, T
    HOIGNE, J
    JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1972, 10 (02): : 581 - &
  • [35] Influences of the polymerization ingredients on the porous morphology of soap-free poly(methyl methacrylate/ethyl acrylate/methacrylic adid) seeded latex particles
    Kang, K
    Kan, CY
    Du, Y
    Liu, DS
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 99 (04) : 1934 - 1939
  • [36] Synthesis and rheological studies of methacrylic acid-ethyl acrylate-allyl methacrylate terpolymers
    Agarwal, Y. K.
    Kaushik, S. D.
    Kumar, P. C.
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2007, 44 (7-9): : 877 - 880
  • [37] Factorial Experimental Design Approach in Semicontinuous Emulsion Polymerization of Methyl Methacrylate to Study the Effect of Process Variables
    Mishra, Sujata
    Singh, Jagbir
    Choudhary, Veena
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (06) : 3742 - 3749
  • [38] Factorial experimental design approach in semicontinuous emulsion polymerization of methyl methacrylate to study the effect of process variables
    Mishra, Sujata
    Singh, Jagbir
    Choudhary, Veena
    Journal of Applied Polymer Science, 2009, 113 (06): : 3742 - 3749
  • [39] In Situ Semibatch Emulsion Polymerization of 2-Ethyl Hexyl Acrylate/n-Butyl Acrylate/Methyl Methacrylate/Cellulose Nanocrystal Nanocomposites for Adhesive Applications
    Ouzas, Alexandra
    Niinivaara, Elina
    Cranston, Emily D.
    Dube, Marc A.
    MACROMOLECULAR REACTION ENGINEERING, 2018, 12 (03)
  • [40] CHLOROSULFONYLATION OF METHACRYLIC ACID AND METHYL METHACRYLATE
    Yurovskaya, M. A.
    Gerasimova, N. P.
    Alov, E. M.
    Danilova, A. S.
    Filimonova, E. I.
    Soboleva, L. M.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2014, 57 (12): : 11 - +
12345