Influence of silicic acid and glauconite on thermal dehydration of Ca(H2PO4)2&middotH2O

被引:0
作者
Tynsuaadu, K. [1 ]
机构
[1] Tallinn Technical Univ, Estonia, Russia
来源
Journal of thermal analysis | 1990年 / 36卷 / 05期
关键词
Chromatographic Analysis - Phosphates--Thermoanalysis - Silicon Compounds - X-Ray Analysis;
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摘要
The thermal dehydration of mixtures of Ca(H2PO4)2&middotH2O with silicic acid and glauconite was studied by thermal (under dynamic and quasi-isothermal-quasi-isobaric conditions), X-ray and chromatographic analyses. It was found that the dehydration of Ca(H2PO4)2&middotH2O is accelerated in the mixtures. SiO2&middotnH2O and glauconite react with the intermediates of dehydration of Ca(H2PO4)2&middotH2O, and silicophosphates and Al, K, Fe-phosphates are formed, respectively. The total degree of polymerization of calcium polyphosphates is lower in the mixtures than in Ca(PO3)2 itself.
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页码:1785 / 1793
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