The thermal dehydration of mixtures of Ca(H2PO4)2·H2O with silicic acid and glauconite was studied by thermal (under dynamic and quasi-isothermal-quasi-isobaric conditions), X-ray and chromatographic analyses. It was found that the dehydration of Ca(H2PO4)2·H2O is accelerated in the mixtures. SiO2·nH2O and glauconite react with the intermediates of dehydration of Ca(H2PO4)2·H2O, and silicophosphates and Al, K, Fe-phosphates are formed, respectively. The total degree of polymerization of calcium polyphosphates is lower in the mixtures than in Ca(PO3)2 itself.