Stereospecific synthesis of C-(2-amino-2-deoxy-β-D-glucosyl) compounds by Wittig-type olefination of D-glucosamine derivatives

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作者
Mbongo, Aime [1 ]
Frechou, Catherine [1 ]
Beaupere, Daniel [1 ]
Uzan, Raoul [1 ]
Demailly, Gilles [1 ]
机构
[1] Univ de Picardio, Amiens, France
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Glucose; -; Synthesis; (chemical);
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摘要
α-C-glycosyl compounds have been obtained selectively from protected 2-acetamido-2-deoxy-D-glucose by a Wittig-type reaction and subsequent cyclization. We studied the behaviour of several pyranose and furanose derivatives of 2-acetamido-2-deoxy-D-glucose towards the Wittig-type reaction in the presence of zinc.
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页码:361 / 370
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