Spin probe study on molecular mobility of interfacial layers in filled polymers

被引：0

作者：

Emanuel Inst. of Biochem. Physics, RAS, ul. Kosygina 4, Moscow, 117977, Russia ^{[1
]}

机构：

来源：

Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya | 2001年 / 43卷 / 11期

关键词：

Adsorption - Electron spin resonance spectroscopy - Free radicals - Glass transition - Phase interfaces - Plastics fillers - Silica;

D O I：

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学科分类号：

摘要：

The molecular mobility of interfacial layers in some polymers filled with silica (Silochrome) was studied using a spin label adsorbed on the surface of the filler particles. It is noted that stable nitroxyl radicals adsorbed on the polymer surface or grafted to the surface can be used. It is established that the differences in molecular mobility between the polymer layers located near the polymer surface and far from the surface sharply decrease with increasing glass transition temperature.

引用

页码：2009 / 2014