Stability constants and related thermodynamic parameters of some quaternary intermacromolecular complexes involving polyelectrolytes and nonionic homopolymers

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Univ of Delhi, Delhi, India [1 ]
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J Macromol Sci Pure Appl Chem | / 1卷 / 157-167期
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Enthalpy - Entropy - Macromolecules - Polyethylene oxides - Polyethylenes - Thermal effects - Thermodynamic stability;
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摘要
Stability constants and related thermodynamic parameters (e.g., ΔH° and ΔS°) of some quaternary intermacromolecular complexes involving polyelectrolytes and nonionic homopolymers were determined at several temperatures. The various interacting forces involved in the complex formation are destabilized at different temperatures which are reflected in the enthalpy and entropy changes of the systems at various temperatures.
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