ELECTROPHILIC ASSISTANCE OF MERCURY(II) IN THE REACTION OF METHYL IODIDE WITH THE TETRACHLOROPLATINITE ANION PROOF FOR AN SN2 MECHANISM OF OXIDATIVE ADDITION.

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作者：

Zamashchikov, V.V.

Litvinenko, S.L.

Uzhik, O.N.

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来源：

Kinetics and Catalysis | 1984年 / 25卷 / 3 pt 2期

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摘要：

The authors observed the effect of electrophilic assistance of mercury(II) in a new reaction involving the oxidative addition of RI to PtCl//4**2** minus , which, as is shown, reduces to the realization of transition state C. The later rigorously proves the S//N//2 mechanism of the reaction presented by the authors at least for conditions of electrophilic assistance in cleaving the carbon-iodine bond. The kinetic equation for a pathway that includes the reaction of MeI simultaneously with platinum(II) and mercury(II) is given.

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页码：653 / 654