THE ELECTRODISSOLUTION KINETICS OF PALLADIUM.

被引：0

作者：

Genesca, Joan ^{[1
]}

Victori, Lluis ^{[1
]}

机构：

[1] UNAM, Mexico City, Mex, UNAM, Mexico City, Mex

来源：

Platinum Metals Review | 1986年 / 30卷 / 02期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - CORROSION - Electrochemical - HYDROCHLORIC ACID - Corrosive Effects;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The anodic dissolution of palladium in deoxygenated acidic chloride solutions has been studied and the reaction order determined. Two reaction mechanisms are proposed, as functions of the pH value. At lower pH, the effect of chloride ion on electro-dissolution kinetics increases as the hydrogen ion concentration increases. In a critical pH region, the adsorption of OH** minus competes with Cl** minus resulting in the formation of PdOH//a//d which then inhibits the corrosion process. 8 Refs.

引用

页码：80 / 83