Temperature dependence of the order parameter in NaK1-x(NH4)xC4H4O6&middot4H2O (x=0.28)

被引:0
作者
Shiozaki, Y. [1 ]
Toki, H. [1 ]
Kabasawa, H. [1 ]
Suzuki, E. [1 ]
Nozaki, R. [1 ]
机构
[1] Hokkaido Univ, Sapporo, Japan
来源
Ferroelectrics | 1996年 / 184卷 / 1 -4 pt 2期
关键词
Crystals - Electric variables measurement - Hysteresis - Polarization - Reflection - Salts - Thermal effects;
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摘要
Long range order parameter of Rochelle salt-ammonium Rochelle salt mixed crystal NaK1-x(NH4)xC4H4O6&middot4H2O, x=0.28 is studied from measuring X-ray Bragg intensity. Additionally the mixed crystal of x=0.27 are studied from observing ferroelectric hysteresis loop. The (050) X-ray Bragg intensity is proportional to (Tc-T) or Ps2. The results give sufficiently good agreement. The critical index β of Ps is obtained to be 0.47 from the hysteresis loop observation, which is almost equal to the value in the mean-field theory. The saturated value of the spontaneous polarization (Ps at T=0 K) is estimated to be 0.57 μF. The spontaneous polarization of other mixed crystals with x=0.56, 0.83 are also measured. The results show that the saturated value of the spontaneous polarization of the mixed crystal increases with increment of x in the range about 0.28<x<0.90.
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页码:301 / 304
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