POLYMER COMMUNICATIONS.

被引：0
|
作者：
Spells, Stephen J.
机构：
来源：
Polymer Communications (Guildford, England) | 1984年 / 25卷 / 06期
关键词：
CRYSTALS - INTERFEROMETERS - MATHEMATICAL TRANSFORMATIONS - Fourier Transforms - SPECTROSCOPY; INFRARED;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The infra-red CD//2 bending vibration in solution-grown isotopically labeled crystals of polyethylene has been analyzed by using Fourier self-deconvolution. Several component peaks are revealed by this technique and the lineshapes are in good agreement with those calculated from a recent model of the author. This lends further support to the model, which involves 75% adjacent re-entry and superfolded sheets of crystal stems diluted by 50% with other molecules. Calculations based on a recent lattice model with 19% adjacent re-entry give much smaller doublet splittings than those observed.
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页码：162 / 166
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