APPLICATION OF NONAQUEOUS ELECTROLYTE SOLUTIONS IN THE ELECTROCHEMICAL TREATMENT OF METALS.

被引:0
作者
Rumyantsev, E.M. [1 ]
Lilin, S.A. [1 ]
Krestov, G.A. [1 ]
Bocharov, A.D. [1 ]
机构
[1] Acad of Sciences of the USSR, Inst, of Chemistry of Nonaqueous, Solutions, Ivanovo, USSR, Acad of Sciences of the USSR, Inst of Chemistry of Nonaqueous Solutions, Ivanovo, USSR
关键词
ELECTROCHEMISTRY - ELECTROLYTES - NICKEL AND ALLOYS - SODIUM CHLORIDE - SOLUTIONS;
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摘要
The first results are presented of systematic investigations of the high-speed anodic dissolution of metals in the example of electrolytic nickel in hydroalcoholic solutions of sodium chloride. The use of mixed hydroalcoholic (or aqueous-organic in the general case) solutions of electrolytes has a number of advantages over nonaqueous solutions, viz. : a) the possibility of obtaining solutions of salts which are poorly soluble or entirely insoluble in the components taken separately, which then have sufficient electrical conductivity; b) the fact that the cosolvents frequently prevent the formation of precipitates, which opens up prospects for the creation of slime-free electrolytes. The investigations were carried out on a rotating disk electrode.
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页码:107 / 109
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