KINETIC MODEL FOR PLASMA ETCHING SILICON IN A SF6/O2 RF DISCHARGE.
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Anderson, H.M.
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Univ of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USAUniv of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USA
Anderson, H.M.
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Merson, J.A.
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Univ of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USAUniv of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USA
Merson, J.A.
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]
Light, R.W.
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Univ of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USAUniv of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USA
Light, R.W.
[1
]
机构:
[1] Univ of New Mexico, Albuquerque, NM,, USA, Univ of New Mexico, Albuquerque, NM, USA
Time-dependent Boltzmann electron distribution calculations have been made at constant power and pressure in a SF//6/O//2 plasma with a varying oxygen mole fraction. The results show that as the oxygen fraction increases in a SF//6/O//2 plasma, the number of high-energy electrons in the tail of the electron distribution and the mean electron energy both increase significantly while the plasma is kept at the same reduced electric field E/N. Rate coefficients have been computed for the electron kinetic processes of these plasmas and merged within a kinetic equilibrium model for the plasma etch process, including neutral gas-phase chemistry, ion chemistry, and surface reactions. Model simulations show good agreement with experimental results for SF//6/O//2 etching of polysilicon and demonstrate that the anisotropic character of dilute SF//6 plasma etching is related to the shift in the electron distribution with increasing oxygen fraction. Ionization rates and ion transport to the surface are shown to be more important.