Relative and absolute configuration of aloperine

被引：0

作者：

Brosius, Arthur D. ^{[1
]}

Ziller, Joseph W. ^{[1
]}

Zhang, Qiming ^{[1
]}

机构：

[1] Univ of California, Irvine, United States

来源：

Acta Crystallographica, Section C: Crystal Structure Communications | 1997年 / 53卷 / pt 10期

关键词：

Aromatic compounds - Conformations - Hydrates - Molecular structure - Salts - X ray analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The relative and absolute configuration of the title compound, (6R,7R,9R,11S)-16,17-didehydro-9-de-2-piperidinylormosanine, C15H24N2, has been elucidated. Two X-ray structures, one of the free base of the alkaloid and the second of its dihydrochloride monohydrate salt, C15H26N22+.2Cl-.H2O, have been determined to unequivocally establish the stereochemistry of aloperine, the parent member of a rare family of lupinine alkaloids.

引用

页码：1510 / 1512