HOMOGENIZATION OF POLYOLEFIN MIXTURES IN SHEAR DEFORMATION.

被引:0
作者
Zhorin, V.A. [1 ]
Mironov, N.A. [1 ]
Nikol'skii, V.G. [1 ]
Yenikolopyan, N.S. [1 ]
机构
[1] Institute of Chemical Physics, U.S.S.R. Academy of Sciences, Russia
来源
Polymer science USSR | 1980年 / 22卷 / 02期
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D O I
10.1016/0032-3950(80)90023-4
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摘要
A study was made of the possibility of homogenization of PE-PP and PP-ethylene propylene rubber mixtures under shear deformation and high pressure. Films of these heterogeneous mixtures were placed on Bridgman anvils and subjected to shear deformation at a pressure of 0. 1-20 kbar and a temperature of 20 degree C. The structure of initial and deformed films was examined by radiothermoluminescence. The initial films had two glass temperatures, which agree with T//g of the components of the mixture. It is shown that deformation at pressures higher than 1 kbar modifies the phase condition of mixtures.
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页码:440 / 447
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