DIFFUSION AND KINETIC STUDIES IN THE PHOTO-CHEMICAL CHLORINATION OF TOLUENE.

被引:0
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作者
Fong, S.K.
Ratcliffe, J.S.
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| 1972年 / MC8卷 / 01期
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DIFFUSION - PHOTOCHEMICAL REACTIONS - REACTION KINETICS;
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摘要
A theoretical examination of the process of diffusion with a chemical reaction having a kinetic expression of first order with respect to the liquid reactant was made based on the steady-state absorption theory. Basic absorption rate equations and the parameters which affect the absorption rates were identified. The heterogeneous chlorination of the toluene side-chain was reduced to a pseudo-homogeneous reaction, under which condition the observed kinetic rate was observed to be of first order with respect to benzal chloride, and independent of any significant chlorine concentration.
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