STUDY OF KINETIC PARAMETER ESTIMATION OF CATALYTIC REFORMING OF C6 HYDROCARBONS.
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作者:
Wu, Jianchu
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机构:
Research Inst of Petroleum, Processing, China, Research Inst of Petroleum Processing, ChinaResearch Inst of Petroleum, Processing, China, Research Inst of Petroleum Processing, China
Wu, Jianchu
[1
]
Lin, Zhengxian
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Research Inst of Petroleum, Processing, China, Research Inst of Petroleum Processing, ChinaResearch Inst of Petroleum, Processing, China, Research Inst of Petroleum Processing, China
Lin, Zhengxian
[1
]
机构:
[1] Research Inst of Petroleum, Processing, China, Research Inst of Petroleum Processing, China
Kinetic simulation and parameter estimation of catalytic reforming at C//6 hydrocarbons have been studied. Totally 12 sets of experimental data were taken in a flow-type reactor system on a commercial Pt-Sn bimetallic catalyst under industrial operating conditions. Care was taken to keep a nearly constant activity and selectivity level of the catalyst. The reaction network was assumed to be composed of benzene, cyclohexane, methylcyclopentane and two lumped compounds, i. e. , hexanes and cracked products. Reaction rate equations of Hougen-Watson type were used to describe the experimental data. (Edited author absract)