Molecular Physical Studies of the Copolymerization Behavior of Vinyl Monomers - 2. Quantum-Chemical Calculations for the Interpretation of the Q-e Scheme of Alfrey and Price.

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作者：

Fleischer, G.

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来源：

Power Engineering (Barrington, Illinois) | 1973年 / 20卷 / 01期

关键词：

MATHEMATICAL TECHNIQUES - POLYMERIZATION - Copolymerization;

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摘要：

The physical backgrounds of Q and e values of the Q-e scheme by Alfrey and Price are investigated by means of quantum-chemical calculations of vinyl monomers and their radicals. The significance of Q as a measure for resonance stabilization could be confirmed. For e a correlation was found with the dipole moments of the monomers and radicals in the direction of the vinyl-C-C bond.

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页码：10 / 15