ON THE DEFORMATION OF POLY(METHYL METHACRYLATE)-POLY(ETHYLENE OXIDE) BLENDS: A MOLECULAR CHARACTERIZATION BY SMALL-ANGLE NEUTRON SCATTERING.

被引:0
作者
Lefebvre, J.-M.R. [1 ]
Porter, Roger S. [1 ]
Wignall, G.D. [1 ]
机构
[1] Univ of Massachusetts, Amherst, MA,, USA, Univ of Massachusetts, Amherst, MA, USA
关键词
PLASTICS; -; Deformation; POLYMERS; Anisotropy;
D O I
暂无
中图分类号
学科分类号
摘要
The deformation behavior of miscible amorphous/amorphous PMMA/PEO poly(methyl methacrylate)/poly(ethylene oxide) blends was compared with that of pure PMMA. Small-angle neutron scattering experiments were performed on labeled systems made of PEO plus D-PMMA plus H-PMMA. Characteristic molecular parameters such as radius of gyration, Rg, molecular weight, M//w, and interaction parameter, chi , were extracted from the coherent scattering cross sections. Molecular anisotropy was measured on the solid state coextruded samples, and the observed drawing efficiency is compared with the results of shrinkage tests.
引用
收藏
页码:433 / 439
相关论文
共 41 条
  • [1] Miscibility in blends of stereoregular poly(methyl methacrylate)/poly(ethylene oxide) based oligomers
    Hamon, L
    Grohens, Y
    Soldera, A
    Holl, Y
    POLYMER, 2001, 42 (24) : 9697 - 9703
  • [2] The solution phase characterization of poly(ferrocenyldimethylsilane)s by small-angle neutron scattering
    Whittell, George R.
    Gilroy, Joe B.
    Grillo, Isabelle
    Manners, Ian
    Richardson, Robert M.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2013, 51 (19) : 4011 - 4020
  • [3] Monoalkyl Poly(2-methyl-2-oxazoline) Micelles. A Small-Angle Neutron Scattering Study
    Volet, Gisele
    Auvray, Loic
    Amiel, Catherine
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (41) : 13536 - 13544
  • [4] Comparison of Cyclic and Linear Poly(lactide)s Using Small-Angle Neutron Scattering
    Yang, Philip B.
    Davidson, Matthew G.
    Edler, Karen J.
    Leaman, Niamh
    Bathke, Elly K.
    McCormick, Strachan N.
    Matsarskaia, Olga
    Brown, Steven
    MACROMOLECULES, 2022, 55 (24) : 11051 - 11058
  • [5] Amorphous and Semicrystalline Blends of Poly(vinylidene fluoride) and Poly(methyl methacrylate): Characterization and Modeling of the Mechanical Behavior
    Halary, J. L.
    Jarray, J.
    Fatnassi, M.
    Larbi, F. Ben Cheikh
    JOURNAL OF ENGINEERING MATERIALS AND TECHNOLOGY-TRANSACTIONS OF THE ASME, 2012, 134 (01):
  • [6] Synthesis and Characterization of Poly(dimethylamino ethyl methacrylate)-Poly(ethylene oxide)-Poly(dimethylamino ethyl methacrylate) Triblock Copolymers
    Tong, Dajun
    Yao, Jia
    Wang, Qing
    Zhai, Tao
    Li, Haoran
    Han, Shijun
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 114 (03) : 1551 - 1556
  • [7] Studies on Thermomechanical Characteristics of Poly(Methyl Methacrylate) and Ethylene-Methyl Acrylate Copolymer Blends
    Poomalai, P.
    Varghese, T. O.
    Siddaramaiah
    POLYMERS & POLYMER COMPOSITES, 2012, 20 (08) : 749 - 754
  • [8] Heterogeneities at the Onset of Reaction Acceleration during Bulk Polymerization of Methyl Methacrylate Investigated by Small-Angle Neutron Scattering
    Suzuki, Yasuhito
    Doi, Yuya
    Mishima, Ryutaro
    Mayumi, Koichi
    Matsumoto, Akikazu
    MACROMOLECULES, 2023, 56 (10) : 3731 - 3738
  • [9] The structure of high-performance polymer blends by small-angle neutron scattering
    Caspar, J
    Dunges, B
    Kirste, RG
    Heitz, T
    Wiedenmann, A
    PHYSICA B, 1997, 234 : 240 - 241