EQUILIBRIUM SILICIDES OF PALLADIUM.

被引：0
作者：
Wysocki, J.A.
Duwez, P.E.
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Metallurgical transactions. A, Physical metallurgy and materials science | 1981年 / 12 A卷 / 08期
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D O I：
10.1007/bf02643690
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摘要：
The Pd-Si system was examined in the 13 to 25 at. % silicon range by X-ray diffraction, thermal analysis, and metallography. The compounds Pd//5Si. Pd//9Si//2, and Pd//3Si form peritectically. Pd//5Si is monoclinic, while Pd//9Si//2 and Pd//3Si are orthorhombic. These compounds form defect structures having low symmetry and large unit cells. Electron concentrations per unit cell govern formation. There was no evidence of either Pd//4Si or Pd//9Si//4.
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页码：1455 / 1460
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