EQUILIBRIUM SILICIDES OF PALLADIUM.

被引：0

作者：

Wysocki, J.A.

Duwez, P.E.

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来源：

Metallurgical transactions. A, Physical metallurgy and materials science | 1981年 / 12 A卷 / 08期

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D O I：

10.1007/bf02643690

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摘要：

The Pd-Si system was examined in the 13 to 25 at. % silicon range by X-ray diffraction, thermal analysis, and metallography. The compounds Pd//5Si. Pd//9Si//2, and Pd//3Si form peritectically. Pd//5Si is monoclinic, while Pd//9Si//2 and Pd//3Si are orthorhombic. These compounds form defect structures having low symmetry and large unit cells. Electron concentrations per unit cell govern formation. There was no evidence of either Pd//4Si or Pd//9Si//4.

引用

页码：1455 / 1460

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