Eine einfache Methode zur Herstellung stannylierter Diaminosulfane

被引:0
作者
Hänssgen, Dieter [1 ]
Plum, Robert [1 ]
机构
[1] Anorganisch-Chemisches Institut der Universität Bonn, Gerhard-Domagk-Straße 1, 1, Bonn,D-5300, Germany
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D O I
10.1002/cber.19871200629
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摘要
A Simple Method for the Preparation of Stannylated Diamino-sulfanes. On heating sulfinimidamides tBuS(NRNR1(SnMe3) (3) (obtained in the stepwise reaction of sulfur diimides 1 with tert-butyllithium and chlorotrimethylstannane) a reductive elimination of isobutene takes place and the stannylated diaminosulfanes (Me3Sn)R1NSNHR2 (4) are formed in good yields. Some properties of these new compounds are reported. Copyright © 1987 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码:1063 / 1064
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