Double dehydrogenative coupling of amino alcohols with primary alcohols under Mn(<sc>i</sc>) catalysis

被引：3
作者：
Sivakumar, Ganesan [1 ]
Suresh, Abhijith Karattil [1 ]
Padhy, Smruti Rekha [1 ]
Balaraman, Ekambaram [1 ]
机构：
[1] Indian Inst Sci Educ & Res IISER Tirupati, Dept Chem, Tirupati 517507, Andhra Prades, India
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 92期
关键词：
RUTHENIUM; CONVERSION; SECONDARY; PYRROLES;
D O I：
10.1039/d4cc03595j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein, we unveil a method for synthesizing substituted pyrrole and pyrazine compounds via a double dehydrogenative coupling of amino alcohols with primary alcohols, facilitated by Mn(i)-PNP catalysis, which uniquely enables the simultaneous formation of C-C and C-N bonds.
引用
收藏
页码：13606 / 13609
页数：4
相关论文
共 58 条
[1]   Phosphine-Free NNN-Manganese Complex Catalyzed α-Alkylation of Ketones with Primary Alcohols and Friedlander Quinoline Synthesis [J].
Barman, Milan K. ;
Jana, Akash ;
Maji, Biplab .
ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (17) :3233-3238
[2]   Iron Catalysis in Organic Synthesis [J].
Bauer, Ingmar ;
Knoelker, Hans-Joachim .
CHEMICAL REVIEWS, 2015, 115 (09) :3170-3387
[3]   Nickel-catalyzed sustainable synthesis of N-heterocycles through dehydrogenative coupling of alcohols [J].
Bera, Krishanu ;
Mukherjee, Arup .
TETRAHEDRON LETTERS, 2021, 81
[4]   Cobalt-catalyzed dehydrogenative functionalization of alcohols: Progress and future prospect [J].
Borthakur, Ishani ;
Sau, Anirban ;
Kundu, Sabuj .
COORDINATION CHEMISTRY REVIEWS, 2022, 451
[5]   Homogeneous Transition Metal Catalysis of Acceptorless Dehydrogenative Alcohol Oxidation: Applications in Hydrogen Storage and to Heterocycle Synthesis [J].
Crabtree, Robert H. .
CHEMICAL REVIEWS, 2017, 117 (13) :9228-9246
[6]   Sustainable Synthesis of Quinazoline and 2-Aminoquinoline via Dehydrogenative Coupling of 2-Aminobenzyl Alcohol and Nitrile Catalyzed by Phosphine-Free Manganese Pincer Complex [J].
Das, Kalicharan ;
Mondal, Avijit ;
Pal, Debjyoti ;
Srimani, Dipankar .
ORGANIC LETTERS, 2019, 21 (09) :3223-3227
[7]   Phosphine free Mn-complex catalysed dehydrogenative C-C and C-heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives [J].
Das, Kalicharan ;
Mondal, Avijit ;
Srimani, Dipankar .
CHEMICAL COMMUNICATIONS, 2018, 54 (75) :10582-10585
[8]   Selective Synthesis of 2-Substituted and 1,2-Disubstituted Benzimidazoles Directly from Aromatic Diamines and Alcohols Catalyzed by Molecularly Defined Nonphosphine Manganese(I) Complex [J].
Das, Kalicharan ;
Mondal, Avijit ;
Srimani, Dipankar .
JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (16) :9553-9560
[9]   Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes [J].
Daw, Prosenjit ;
Kumar, Amit ;
Espinosa-Jalapa, Noel Angel ;
Diskin-Posner, Yael ;
Ben-David, Yehoshoa ;
Milstein, David .
ACS CATALYSIS, 2018, 8 (09) :7734-7741
[10]   Direct Synthesis of Pyrroles by Dehydrogenative Coupling of Diols and Amines Catalyzed by Cobalt Pincer Complexes [J].
Daw, Prosenjit ;
Chakraborty, Subrata ;
Garg, Jai Anand ;
Ben-David, Yehoshoa ;
Milstein, David .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (46) :14371-14375
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