Mononuclear lanthanide single-molecule magnets based on polyoxometalates

被引：0
|
作者：
AlDamen, Murad A. [1 ]
Clemente-Juan, Juan M. [1 ,3 ]
Coronado, Eugenio [1 ]
Martí-Gastaldo, Carlos [1 ]
Gaita-Ariño, Alejandro [1 ,2 ]
机构：
[1] Instituto de Ciencia Molecular, Universidad de Valencia, Polígono de la Coma s/n, 46980 Paterna, Spain
[2] Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, BC V6T 1Z1, Canada
[3] Fundación General Universidad de Valencia (FGUV), Plaça del Patriarca, 46002 Valencia, Spain
来源：
Journal of the American Chemical Society | 2008年 / 130卷 / 28期
关键词：
ErW10O36]9- is the first polyoxometalate behaving as a single-molecule magnet (SMM). It shows frequency-dependent out-of-phase magnetization and a thermally activated single relaxation process with an effective barrier of 55.8 K. This single lanthanide ion polyoxometalate is the inorganic analogue of the bis(phthalocyaninato)lanthanide SMMs; both exhibiting very similar ligand field symmetries around the lanthanide ion (idealized D4d). It is chemically stable and offers new avenues for organization and processing of single-molecule magnets. Furthermore; it can be made free from nuclear spins and opens the possibility to be used for studies of decoherence on unimolecular qubits. Copyright © 2008 American Chemical Society;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：8874 / 8875
相关论文
共 50 条
  • [41] Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide-Based Single-Molecule Magnets
    Bernot, Kevin
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 26 (35)
  • [42] A series of heterometallic 3d-4f polyoxometalates as single-molecule magnets
    Li, Shurong
    Weng, Zhenzhang
    Jiang, Linpeng
    Wei, Rongjia
    Su, Haifeng
    Long, Lasheng
    Zheng, Lansun
    Kong, Xiangjian
    CHINESE CHEMICAL LETTERS, 2023, 34 (03)
  • [43] A series of heterometallic 3d-4f polyoxometalates as single-molecule magnets
    Shurong Li
    Zhenzhang Weng
    Linpeng Jiang
    Rongjia Wei
    Haifeng Su
    Lasheng Long
    Lansun Zheng
    Xiangjian Kong
    ChineseChemicalLetters, 2023, 34 (03) : 467 - 470
  • [44] Fine Control of the Metal Environment within Dysprosium-Based Mononuclear Single-Molecule Magnets
    Guettas, Djamila
    Montigaud, Vincent
    Garcia, Guglielmo Fernandez
    Larini, Paolo
    Cador, Olivier
    Le Guennic, Boris
    Pilet, Guillaume
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (3-4) : 333 - 339
  • [45] Single-molecule magnets evolve
    Ritter, SK
    CHEMICAL & ENGINEERING NEWS, 2004, 82 (50) : 29 - 32
  • [46] Development of Single-Molecule Magnets†
    Shao, Dong
    Wang, Xin-Yi
    CHINESE JOURNAL OF CHEMISTRY, 2020, 38 (09) : 1005 - 1018
  • [47] Single-Molecule Magnets on Surfaces
    Cornia, Andrea
    Mannini, Matteo
    MOLECULAR NANOMAGNETS AND RELATED PHENOMENA, 2015, 164 : 293 - 330
  • [48] SINGLE-MOLECULE MAGNETS EVOLVE
    Ritter, Steve
    CHEMICAL & ENGINEERING NEWS, 2011, 89 (13) : 8 - 8
  • [49] Single-molecule magnets.
    Hendrickson, DN
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U147 - U147
  • [50] Spectroscopy of single-molecule magnets
    McInnes, Eric J. L.
    SINGLE-MOLECULE MAGNETS AND RELATED PHENOMENA, 2006, 122 : 69 - 102
12345