Evaluation of a Non-Enzymatic Electrochemical Sensor Based on Co(OH)2-Functionalized Carbon Nanotubes for Glucose Detection

被引:0
|
作者
Bolanos-Mendez, Diego [1 ]
Fernandez, Lenys [1 ]
Uribe, Rafael [2 ]
Cunalata-Castro, Alisson [1 ]
Gonzalez, Gema [3 ]
Rojas, Isamara [2 ]
Chico-Proano, Andres [2 ]
Debut, Alexis [4 ]
Celi, Luis Alberto [2 ]
Espinoza-Montero, Patricio [1 ]
机构
[1] Pontificia Univ Catolica Ecuador, Escuela Ciencias Quim, Quito 170525, Ecuador
[2] Escuela Politec Nacl, Dept Ingn Quim, Quito 170525, Ecuador
[3] Univ Yachay Tech, Escuela Ciencias Fis & Nanotecnol, Urcuqui 100650, Ecuador
[4] Univ Fuerzas Armadas ESPE, Ctr Nanociencia & Nanotecnol, Sangolqui 170501, Ecuador
关键词
carbon nanotubes; cobalt hydroxide; glucose; electrochemical sensors; non-enzymatic; GLASSY-CARBON; RAMAN-SPECTROSCOPY; ELECTRODE; PERFORMANCE; DEPOSITION; ARRAY;
D O I
10.3390/s24237707
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This work reports on the assessment of a non-hydrolytic electrochemical sensor for glucose sensing that is developed using functionalized carbon nanotubes (fCNTs)/Co(OH)2. The morphology of the nanocomposite was investigated by scanning electron microscopy, which revealed that the CNTs interacted with Co(OH)2. This content formed a nanocomposite that improved the electrochemical characterizations of the electrode, including the electrochemical active surface area and capacitance, thus improving sensitivity to glucose. In the electrochemical characterization by cyclic voltammetry and chronoamperometry, the increase in catalytic activity by Co(OH)2 improved the stability and reproducibility of the glucose sensor without the use of enzymes, and its concentration range was between 50 and 700 mu mol L-1. The sensor exhibited good linearity towards glucose with LOD value of 43.200 mu mol L-1, which proved that the Co(OH)2-fCNTs composite is judicious for constructing cost effective and feasible sensor for glucose detection.
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页数:17
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