Domain configuration changes under electric field-induced antiferroelectric-ferroelectric phase transitions in NaNbO3-based ceramics

被引：0
|
作者：
机构：
[1] Guo, Hanzheng
[2] Shimizu, Hiroyuki
[3] Mizuno, Youichi
[4] Randall, Clive A.
来源：
Guo, Hanzheng (hug17@psu.edu) | 1600年 / American Institute of Physics Inc.卷 / 118期
关键词：
We recently developed a feasible crystal chemistry strategy to stabilize the antiferroelectricity in NaNbO3 through a chemical substitution to decrease the tolerance factor and increase the average electronegativity of the system [Shimizu et al; Dalton Trans. 44; 10763 (2015) and Guo et al; J; Appl; Phys; 117; 214103 (2015)]. Two novel lead-free antiferroelectric (AFE) solid solutions; (1-x)NaNbO3-xCaZrO3; and; (1-x)NaNbO3-xSrZrO3; have been found to exhibit the double polarization hysteresis typical of a reversible AFE → ferroelectric (FE) phase transition. In this study; as demonstrated by (1-x)NaNbO3-xCaZrO3 system; the influence of chemical modification and electrical poling on the AFE/FE phase stability was investigated; primarily focusing on the microstructural and crystallographic evolutions. Together with the macroscopic polarization hysteresis measurements; a well-demonstrated structure-property relationship was presented. It was found that the CaZrO3 substitution into NaNbO3 can effectively destabilize the FE Q phase and correspondingly lead to a spontaneous reverting to AFE P phase. In contrast to the reversible AFE → FE phase transition; the domain morphology evolution exhibits irreversible nature with a growing process of the orientational domains after applying electric field. Moreover; a multiple-zone axes electron diffraction map of P and Q phases has been summarized and is believed to be an efficient diagram to determine the AFE/FE nature of the NaNbO3-based systems. © 2015 AIP Publishing LLC;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
引用
收藏
相关论文
共 50 条
  • [21] Field-induced antiferroelectric-ferroelectric phase transitions in the Pb0.98La0.02(Zr0.70Hf0.30 )1 - XTixO3 system
    Heremans, Catherine
    Tuller, Harry L.
    1600, American Institute of Physics Inc. (87):
  • [22] Superior energy storage performance in NaNbO3-based lead-free ceramics under low electric field
    Liu, Kun
    Peng, Ping
    Lv, Zhongqian
    Nie, Hengchang
    Wang, Genshui
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2025, 108 (02)
  • [23] Field-induced antiferroelectric-ferroelectric phase transitions in the Pb0.98La0.02(Zr0.70Hf0.30)1-xTixO3 system
    Heremans, C
    Tuller, HL
    JOURNAL OF APPLIED PHYSICS, 2000, 87 (03) : 1458 - 1466
  • [24] SUPERHIGH FIELD-INDUCED PHASE-TRANSITIONS IN NANBO3 CRYSTALS
    ULINZHEYEV, AV
    FESENKO, OE
    SMOTRAKOV, VG
    FERROELECTRICS LETTERS SECTION, 1990, 12 (01) : 17 - 21
  • [25] Influence of Composition and Pressure on the Electric Field-Induced Antiferroelectric to Ferroelectric Phase Transformation in Lanthanum Modified Lead Zirconate Titanate Ceramics
    Pelaiz-Barranco, Aime
    Hall, David A.
    IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL, 2009, 56 (09) : 1785 - 1791
  • [26] Record-breaking electrostrain in NaNbO3-based antiferroelectric ceramics via achieving fully reversible phase transition
    Ma, Li
    Che, Zhiyi
    Luo, Yuanyuan
    Xu, Chao
    Cen, Zhenyong
    Toyohisa, Fujita
    Zhang, Shujun
    Li, Jing-Feng
    Luo, Nengneng
    ACTA MATERIALIA, 2025, 289
  • [27] Antiferroelectric orthorhombic P-to-R phase transition induced exotic electrocaloric effect in NaNbO3-based lead-free ceramics
    Li, Feng
    Liu, Wei
    Ma, Jianxing
    Long, Mingsheng
    Lou, Xiaojie
    Li, Kai
    Wang, Chunchang
    Shan, Lei
    APPLIED PHYSICS LETTERS, 2023, 122 (09)
  • [28] Giant and reversible photoluminescence modulation based on in situ electric-field-controlled antiferroelectric-ferroelectric phase transition
    Zhang, Yu
    Huang, Ying
    Xue, Wuming
    Wu, Xiao
    Zhao, Chunlin
    Lin, Tengfei
    Lin, Cong
    Gao, Min
    JOURNAL OF MATERIALS CHEMISTRY C, 2022, 10 (40) : 14946 - 14954
  • [29] Antiferroelectric-ferroelectric crossover induced by composition variation in AgNbO3-based lead-free ceramics
    Tian, Tingfang
    Chen, Feilong
    Wen, Zhaokuan
    Wang, Zhiguo
    Hu, Yongming
    Shu, Shengwen
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2023, 34 (04)
  • [30] Field-induced antiferroelectric-to-ferroelectric phase transition of lead niobium zirconate titanate stannate ceramics
    RICOH Co, Ltd, Yokohama, Japan
    Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes & Review Papers, 1997, 36 (9 B): : 5997 - 6000
12345