Influence of Candle Emissions on Monoterpene Oxidation Chemistry and Secondary Organic Aerosol

被引：0

作者：

Wang, Kai ^{[1
,2
]}

Rasmussen, Berit Brondum ^{[1
]}

Thomsen, Ditte ^{[1
]}

Zhang, Yun ^{[3
,4
]}

Jensen, Mads Mork ^{[1
]}

Kristensen, Kasper ^{[5
]}

Hoffmann, Thorsten ^{[3
]}

Glasius, Marianne ^{[1
]}

Bilde, Merete ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[2] China Agr Univ, Coll Resources & Environm Sci, State Key Lab Nutrient Use & Management, Natl Acad Agr Green Dev,Natl Observ & Res Stn Agr, Beijing 100193, Peoples R China

[3] Johannes Gutenberg Univ Mainz, Inst Inorgan & Analyt Chem, D-55128 Mainz, Germany

[4] China Agr Univ, Coll Sci, Innovat Ctr Pesticide Res, Dept Appl Chem, Beijing 100193, Peoples R China

[5] Aarhus Univ, Dept Biol & Chem Engn, DK-8000 Aarhus C, Denmark

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2024年 / 58卷 / 48期

关键词：

indoor air pollutants; candle emission; alpha-pineneozonolysis; particle formation; chemical composition; INDOOR ENVIRONMENTS; ALPHA-PINENE; EXPOSURE ASSESSMENT; PARTICLE FORMATION; D-LIMONENE; OZONE; OZONOLYSIS; NO3; AIR; PRODUCTS;

D O I：

10.1021/acs.est.4c04075

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Candle burning is a considerable contributor to indoor pollutants, while secondary organic aerosols (SOA) from monoterpene ozonolysis represent another type. However, knowledge of the interactions of different indoor pollutants is limited. We investigated physicochemical properties of SOA generated from typical indoor chemistry of the O3/alpha-pinene reaction with and without the presence of particles and gases from a burning candle. Ozonolysis of alpha-pinene in the presence of candle gaseous emissions yielded a considerably lower particle number, larger particle sizes, and lower particle oxygen-to-carbon ratio compared with experiments without candle emissions. More nitrogen-containing organic compounds were observed in the aerosol phase with candle emissions. Furthermore, concentrations of some typical particle-phase products from the O3/alpha-pinene reaction (i.e., terebic acid, cis-pinic acid, and 3-methyl-1,2,3-butanetricarboxylic acid) were less abundant in the presence of candle emissions. The predicted volatility of particulate organic compounds was higher in experiments with candle emissions. The study demonstrates that candle burning can affect the chemical and physical properties of particles formed from other sources (e.g., alpha-pinene ozonolysis) by affecting gas-phase chemistry and gas-particle partitioning.

引用

页码：21265 / 21274

页数：10

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