Preparation of monodispersed Cu nanoparticles by microwave-assisted alcohol reduction

被引：0
|
作者：
Nakamura, Takashi [1 ]
Tsukahara, Yasunori [3 ]
Sakata, Takao [4 ]
Mori, Hirotaro [4 ]
Kanbe, Yumi [5 ]
Bessho, Hisami [5 ]
Wada, Yuji [2 ,3 ]
机构：
[1] Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
[2] Department of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushima-Naka, Okayama 700-8530
[3] Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871
[4] Research Center for Ultra-High Voltage Electron Microscopy, Osaka University, 7-1 Mihogaoka, Ibaraki, Osaka 567-0047
[5] Tokai Rubber Industries Ltd., 3-1 Higashi, Komaki 485-8550
来源：
Bulletin of the Chemical Society of Japan | 2007年 / 80卷 / 01期
关键词：
Copper (Cu) nanoparticles were prepared via a microwave-assisted alcohol reduction process. We have succeeded in selectively preparing monodispersed Cu nanoparticles with or without surface plasmon absorption. Monodispersed Cu nanoparticles with average sizes of 5-6 nm (with the surface plasmon absorption) and 2-3 nm (without the surface plasmon absorption) were prepared using copper(II) octanoate and copper(II) myristate; respectively; as the copper precursors by reduction with alcohols under microwave-heating at 443K for 20 min. Noteworthy; Cu2O and CuO were not observed in the electron diffraction patterns of the prepared Cu nanoparticles; demonstrating chemical stability of the nanoparticles against oxidation in air. When using a long-chain carboxylate as an organic moiety bearing a short alkyl chain (copper(II) octanoate); the rate of the reduction was faster than long one (copper(II) myristate). The activation energies for the reduction of Cu2+ using copper(II) octanoate and copper(II) myristate were estimated to be 115 and 124 kJ mol-1; respectively. We have shown that the length of the alkyl chain contained in the copper precursors; heating temperature; and microwave-irradiation time are important for rapidly preparing monodispersed Cu nanoparticles. © 2007 The Chemical Society of Japan;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：224 / 232
相关论文
共 50 条
  • [1] Preparation of monodispersed Cu nanoparticles by microwave-assisted alcohol reduction
    Nakamura, Takashi
    Tsukahara, Yasunori
    Sakata, Takao
    Mori, Hirotaro
    Kanbe, Yumi
    Bessho, Hisami
    Wada, Yuji
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (01) : 224 - 232
  • [2] Preparation of Ag core-Cu shell nanoparticles by microwave-assisted alcohol reduction process
    Nakamura, Takashi
    Tsukahara, Yasunori
    Yamauchi, Tomohisa
    Sakata, Takao
    Mori, Hirotaro
    Wada, Yuji
    CHEMISTRY LETTERS, 2007, 36 (01) : 154 - 155
  • [3] Microwave-assisted preparation of silver nanoparticles
    Yamamoto, T
    Wada, Y
    Sakata, T
    Mori, H
    Goto, M
    Hibino, S
    Yanagida, S
    CHEMISTRY LETTERS, 2004, 33 (02) : 158 - 159
  • [4] Microwave-assisted polyol synthesis of Cu nanoparticles
    Blosi, M.
    Albonetti, S.
    Dondi, M.
    Martelli, C.
    Baldi, G.
    JOURNAL OF NANOPARTICLE RESEARCH, 2011, 13 (01) : 127 - 138
  • [5] Microwave-assisted polyol synthesis of Cu nanoparticles
    M. Blosi
    S. Albonetti
    M. Dondi
    C. Martelli
    G. Baldi
    Journal of Nanoparticle Research, 2011, 13 : 127 - 138
  • [6] Preparation of CdS nanoparticles by microwave-assisted synthesis
    Tamasauskaite-Tamasiunaite, L.
    Grinciene, G.
    Simkunaite-Stanyniene, B.
    Naruskevicius, L.
    Pakstas, V.
    Selskis, A.
    Norkus, E.
    CHEMIJA, 2015, 26 (03): : 193 - 197
  • [7] Microwave-assisted synthesis of monodispersed CdTe nanocrystals
    Song, Qing
    Ai, Xin
    Topuria, Teya
    Rice, Philip M.
    Alharbi, Fahhad H.
    Bagabas, Abdulaziz
    Bahattab, Muhamad
    Bass, John D.
    Kim, Ho-Cheol
    Scott, J. Campbell
    Miller, Robert D.
    CHEMICAL COMMUNICATIONS, 2010, 46 (27) : 4971 - 4973
  • [8] Microwave Assisted Preparation and Characterization of Monodispersed PbSe Nanoparticles in Solar Cell
    Wang Xiaofeng
    Lue Weizhong
    Luo Zhongkuan
    Wang Fang
    RARE METAL MATERIALS AND ENGINEERING, 2010, 39 : 103 - 106
  • [9] Microwave-assisted synthesis of spherical monodispersed magnesium fluoride
    Pietrowski, Mariusz
    Wojciechowska, Maria
    JOURNAL OF FLUORINE CHEMISTRY, 2007, 128 (03) : 219 - 223
  • [10] Preparation and characterization of ceria nanoparticles by microwave-assisted solvothermal process
    Zawadzki, Miroslaw
    Journal of Alloys and Compounds, 2008, 454 (1-2): : 347 - 351
12345