Neutral mononuclear indium(<sc>iii</sc>) photosensitizers for CO2 photoreduction

被引：0

作者：

Zhang, Zaichao ^{[1
]}

Fu, Li-Zhi ^{[2
]}

He, Piao ^{[2
]}

Yi, Xiao-Yi ^{[2
]}

机构：

[1] Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China

[2] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 44期

关键词：

COORDINATION-COMPOUNDS; PHOTOCHEMISTRY; PHOTOPHYSICS; REDUCTION; METALS;

D O I：

10.1039/d4dt02595d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, neutral mononuclear indium(iii) complexes (In-1-In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO2 reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)32+. The amount of CO generation is 28.4 mu mol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH3CN media.

引用

页码：17772 / 17776

页数：5