Neutral mononuclear indium(<sc>iii</sc>) photosensitizers for CO2 photoreduction

被引：0
作者：
Zhang, Zaichao [1 ]
Fu, Li-Zhi [2 ]
He, Piao [2 ]
Yi, Xiao-Yi [2 ]
机构：
[1] Huaiyin Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China
[2] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
来源：
DALTON TRANSACTIONS | 2024年 / 53卷 / 44期
关键词：
COORDINATION-COMPOUNDS; PHOTOCHEMISTRY; PHOTOPHYSICS; REDUCTION; METALS;
D O I：
10.1039/d4dt02595d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein, neutral mononuclear indium(iii) complexes (In-1-In-3) containing 2,6-di(1H-pyrrol-2-yl)pyridine and substituted dipyridylpyrrole pincer ligand were employed as photosensitizers (PS) in photocatalytic CO2 reduction. In-2 exhibits good photo-activity and selectivity, which is superior to the classic PS Ru(bpy)32+. The amount of CO generation is 28.4 mu mol with a CO selectivity of 93% when using In-2 as a PS and CoPc as a catalyst in CH3CN media.
引用
收藏
页码：17772 / 17776
页数：5
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