Effect of bisphenol A on the miscibility, phase morphology, and specific interaction in immiscible biodegradable poly(Ε-caprolactone)/poly(L-lactide) blends

被引：0
|
作者：
Kuo, Shiao-Wei [1 ]
Huang, Chih-Feng [1 ]
Tung, Yi-Chih [1 ]
Chang, Feng-Chih [1 ]
机构：
[1] Institute of Applied Chemistry, National Chiao Tung University, Hsin Chu, Taiwan
来源：
Journal of Applied Polymer Science | 2006年 / 100卷 / 02期
关键词：
We have investigated the enhancement in irascibility; upon addition of bisphenol A (BPA) of immiscible binary biodegradable blends of poly(Ε-caprolactone) (PCL) and poly(L-lactide) (PLLA). That BPA is miscible with both PCL and PLLA was proven by the single value of Tg observed by differential scanning calorimetry (DSC) analyses over the entire range of compositions. At various compositions and temperatures; Fourier transform infrared spectroscopy confirmed that intermolecular hydrogen bonding existed between the hydroxyl group of BPA and the carbonyl groups of PCL and PLLA. The addition of BPA enhances the miscibility of the immiscible PCL/PLLA binary blend and transforms it into a miscible blend at room temperature when a sufficient quantity of the BPA is present. In addition; optical microscopy (OM) measurements of the phase morphologies of ternary BPA/PCL/PLLA blends at different temperatures indicated an upper critical solution temperature (UCST) phase diagram; since the ΔK effect became smaller at higher temperature (200°C) than at room temperature. An analysis of infrared spectra recorded at different temperatures correlated well with the OM analyses. © 2006 Wiley Periodicals; Inc;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：1146 / 1161
相关论文
共 50 条
  • [1] Effect of bisphenol A on the miscibility, phase morphology, and specific interaction in immiscible biodegradable poly(ε-caprolactone)/poly(L- lactide) blends
    Kuo, SW
    Huang, CF
    Tung, YC
    Chang, FC
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 100 (02) : 1146 - 1161
  • [2] Miscibility and Crystallization of Poly(L-lactide)/Poly(ethylene glycol) and Poly(L-lactide)/Poly(ε-caprolactone) Blends
    Jen-Ming Yang
    Hsin-Lung Chen
    Jiang-Wen You
    Jenn Chiu Hwang
    Polymer Journal, 1997, 29 : 657 - 662
  • [3] Immiscible poly(L-lactide)/poly(ε-caprolactone) blends:: Influence of the addition of a poly(L-lactide) -poly(oxyethylene) block copolymer on thermal behavior and morphology
    Maglio, G
    Malinconico, M
    Migliozzi, A
    Groeninckx, G
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2004, 205 (07) : 946 - 950
  • [4] Miscibility and crystallization of poly(L-lactide) poly(ethylene glycol) and poly(L-lactide)/poly(epsilon-caprolactone) blends
    Yang, JM
    Chen, HL
    You, JW
    Hwang, JC
    POLYMER JOURNAL, 1997, 29 (08) : 657 - 662
  • [5] LCST phase separation in biodegradable polymer blends:: poly(D,L-lactide) and poly(ε-caprolactone)
    Meredith, JC
    Amis, EJ
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2000, 201 (06) : 733 - 739
  • [6] Miscibility and specific interactions in blends of poly(L-lactide) with poly(vinylphenol)
    Meaurio, E
    Zuza, E
    Sarasua, JR
    MACROMOLECULES, 2005, 38 (04) : 1207 - 1215
  • [7] Miscibility and morphology of binary crystalline blends of poly(L-lactide) and poly(butylene adipate)
    Lifen Zhao
    Xinyu Peng
    Xin Liu
    Yanmin Wang
    Shengxue Qin
    Jun Zhang
    Polymer Journal, 2013, 45 : 929 - 937
  • [8] Miscibility and morphology of binary crystalline blends of poly(L-lactide) and poly(butylene adipate)
    Zhao, Lifen
    Peng, Xinyu
    Liu, Xin
    Wang, Yanmin
    Qin, Shengxue
    Zhang, Jun
    POLYMER JOURNAL, 2013, 45 (09) : 929 - 937
  • [9] Miscibility and properties of linear poly(L-lactide)/branched poly(L-lactide) copolyester blends
    Zuideveld, Mihaela
    Gottschalk, Carsten
    Kropfinger, Heidi
    Thomann, Ralf
    Rusu, Mihai
    Frey, Holger
    POLYMER, 2006, 47 (11) : 3740 - 3746
  • [10] The crystallization and miscibility of poly(L-lactide)/poly(DL-lactide) blends
    Liao, KR
    Quan, DP
    Gao, JW
    Luo, BH
    Lu, ZJ
    ACTA POLYMERICA SINICA, 2002, (02) : 137 - 141
12345