Fluorinated acrylic polymers: Surface properties and XPS investigations

被引：0
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作者：
Saïdi, Salima [1 ]
Guittard, Frédéric [1 ]
Guimon, Claude [2 ]
Géribaldi, Serge [1 ]
机构：
[1] Laboratoire de Chimie des Matériaux Organiques et Métalliques, Université de Nice-Sophia Antipolis, Faculté des Sciences, Parc Valrose, 06108 Nice Cedex 2, France
[2] Laboratoire de Physico-Chimie Moléculaire, UMR 5624 CNRS, Université de Pau et des Pays de l'Adour, 2 Av. Angot, 64053 Pau Cedex 9, France
来源：
Journal of Applied Polymer Science | 1600年 / 99卷 / 03期
关键词：
A series of polymers based on methylmethacrylate; butylacrylate; and ω-perfluorooctylalkylacrylate were prepared by radical polymerization. By changing both the length of the hydrocarbon spacer; between the fluorinated chain and the ester function of the fluorinated monomer; and its concentration; the surface properties of the resulting terpolymers were greatly influenced. Polymers containing small amounts of fluorinated comonomer units had considerably reduced surface energies compared to the copolymer poly (methylmethacrylate-co-butylacrylate) taken as reference. The outermost surface composition has been investigated by the XPS technique; confirming the strong fluorine enrichment. © 2005 Wiley Periodicals; Inc;
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页码：821 / 827
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