Fluorinated acrylic polymers: Surface properties and XPS investigations

被引：0
|
作者：
Saïdi, Salima [1 ]
Guittard, Frédéric [1 ]
Guimon, Claude [2 ]
Géribaldi, Serge [1 ]
机构：
[1] Laboratoire de Chimie des Matériaux Organiques et Métalliques, Université de Nice-Sophia Antipolis, Faculté des Sciences, Parc Valrose, 06108 Nice Cedex 2, France
[2] Laboratoire de Physico-Chimie Moléculaire, UMR 5624 CNRS, Université de Pau et des Pays de l'Adour, 2 Av. Angot, 64053 Pau Cedex 9, France
来源：
Journal of Applied Polymer Science | 1600年 / 99卷 / 03期
关键词：
A series of polymers based on methylmethacrylate; butylacrylate; and ω-perfluorooctylalkylacrylate were prepared by radical polymerization. By changing both the length of the hydrocarbon spacer; between the fluorinated chain and the ester function of the fluorinated monomer; and its concentration; the surface properties of the resulting terpolymers were greatly influenced. Polymers containing small amounts of fluorinated comonomer units had considerably reduced surface energies compared to the copolymer poly (methylmethacrylate-co-butylacrylate) taken as reference. The outermost surface composition has been investigated by the XPS technique; confirming the strong fluorine enrichment. © 2005 Wiley Periodicals; Inc;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：821 / 827
相关论文
共 50 条
  • [31] The Chemical Composition of the Near-Surface Layer of Metal Substrates According to XPS Data and Its Effect on the Physical-Mechanical Properties of Acrylic Polymers
    T. R. Aslamazova
    O. D. Grafov
    V. A. Kotenev
    Protection of Metals and Physical Chemistry of Surfaces, 2022, 58 : 1141 - 1149
  • [32] New fluorinated acrylic polymers for improving weatherability of building stone materials
    Ciardelli, F
    Aglietto, M
    di Mirabello, LM
    Passaglia, E
    Giancristoforo, S
    Castelvetro, V
    Ruggeri, G
    PROGRESS IN ORGANIC COATINGS, 1997, 32 (1-4) : 43 - 50
  • [33] Investigation on the thermal degradation of acrylic polymers with fluorinated side-chains
    Zuev, VV
    Bertini, F
    Audisio, G
    POLYMER DEGRADATION AND STABILITY, 2006, 91 (03) : 512 - 516
  • [34] New fluorinated acrylic polymers for improving weatherability of building stone materials
    Ciardelli, F
    Aglietto, M
    di Mirabello, LM
    Passaglia, E
    Giancristoforo, S
    Castelvetro, V
    Ruggeri, G
    XXIIND INTERNATIONAL CONFERENCE IN ORGANIC COATINGS - WATERBORNE - HIGH SOLIDS - POWDER COATINGS, 1996, : 65 - 79
  • [35] Properties of low surface energy fluorocarbon polymers with fluoro-acrylic resins
    Xiusheng Liu
    Can Wang
    Lanxuan Liu
    Jian Li
    Wanzhen Gao
    Journal of Wuhan University of Technology-Mater. Sci. Ed., 2008, 23 : 285 - 288
  • [36] Analyzing the surface properties of acrylic-based water-soluble polymers
    Yazici, Demet Topaloglu
    Cetinkaya, Hayrullah
    Soelener, Musa
    Albayrak, Adile
    INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, 2017, 22 (06) : 483 - 489
  • [37] Properties of low surface energy fluorocarbon polymers with fluoro-acrylic resins
    Liu Xinsheng
    Wang Can
    Liu Lanxuan
    Li Jian
    Gao Wanzhen
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2008, 23 (03): : 285 - 288
  • [38] XPS characterization of surface functionalized electroactive polymers
    Loh, FC
    Tan, KL
    Kang, ET
    Kato, K
    Uyama, Y
    Ikada, Y
    SURFACE AND INTERFACE ANALYSIS, 1996, 24 (09) : 597 - 604
  • [39] SURFACE CHARACTERIZATION OF POLYMERS BY XPS AND SIMS TECHNIQUES
    Kovac, Janez
    MATERIALI IN TEHNOLOGIJE, 2011, 45 (03): : 191 - 197
  • [40] DIELECTRIC-PROPERTIES OF FLUORINATED POLYMERS
    SACHER, E
    JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1981, B19 (01): : 109 - 129
12345