Fluorinated acrylic polymers: Surface properties and XPS investigations

被引：0
|
作者：
Saïdi, Salima [1 ]
Guittard, Frédéric [1 ]
Guimon, Claude [2 ]
Géribaldi, Serge [1 ]
机构：
[1] Laboratoire de Chimie des Matériaux Organiques et Métalliques, Université de Nice-Sophia Antipolis, Faculté des Sciences, Parc Valrose, 06108 Nice Cedex 2, France
[2] Laboratoire de Physico-Chimie Moléculaire, UMR 5624 CNRS, Université de Pau et des Pays de l'Adour, 2 Av. Angot, 64053 Pau Cedex 9, France
来源：
Journal of Applied Polymer Science | 1600年 / 99卷 / 03期
关键词：
A series of polymers based on methylmethacrylate; butylacrylate; and ω-perfluorooctylalkylacrylate were prepared by radical polymerization. By changing both the length of the hydrocarbon spacer; between the fluorinated chain and the ester function of the fluorinated monomer; and its concentration; the surface properties of the resulting terpolymers were greatly influenced. Polymers containing small amounts of fluorinated comonomer units had considerably reduced surface energies compared to the copolymer poly (methylmethacrylate-co-butylacrylate) taken as reference. The outermost surface composition has been investigated by the XPS technique; confirming the strong fluorine enrichment. © 2005 Wiley Periodicals; Inc;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：821 / 827
相关论文
共 50 条
  • [21] Surface Properties and Protein Adsorption Performance of Fluorinated Amphiphilic Polymers
    Zhu, Benfeng
    Yang, Jingjing
    Liu, Jiao
    Meng, Yanbin
    Du, Xiaoqing
    Cai, Chao
    Zhang, Zhao
    JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (20): : 12773 - 12780
  • [22] XPS studies of fluorinated acrylate polymers and block copolymers with polystyrene
    Kassis, CM
    Steehler, JK
    Betts, DE
    Guan, ZB
    Romack, TJ
    DeSimone, JM
    Linton, RW
    MACROMOLECULES, 1996, 29 (09) : 3247 - 3254
  • [23] Partially fluorinated acrylic copolymers as coatings for stone protection: characterization and surface properties
    Toniolo, L
    Della Volpe, C
    Brugnara, M
    Poli, T
    MATERIALS ISSUES IN ART AND ARCHAEOLOGY VI, 2002, 712 : 91 - 97
  • [24] PREPARATION AND SURFACE PROPERTIES OF ACRYLIC COPOLYMERS CONTAINING FLUORINATED MONOMERS附视频
    Taijiang Gui Hao Wei Ying Zhao Xiulin Wang Dujin Wang and Duanfu Xu Chemistry and Chemical Engineering College Ocean University of China Qingdao China State Key Laboratory of Polymer Physics and Chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences Beijing China Marine Research Institute of Chemical Industry Qingdao China
    Chinese Journal of Polymer Science, 2006, (06) : 575 - 578
  • [25] Degradation of fluorinated acrylic polymers in supercritical CO2.
    Yashiro, H
    Forbes, MDE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U278 - U278
  • [26] Angle-resolved XPS of fluorinated and semi-fluorinated side-chain polymers
    Beamson, G
    Alexander, MR
    SURFACE AND INTERFACE ANALYSIS, 2004, 36 (04) : 323 - 333
  • [27] Synthesis and surface properties of a new fluorinated acrylic diblock copolymer via AGET ATRP
    Yanjuan Guo
    Weiqu Liu
    Polymer Science Series B, 2016, 58 : 313 - 320
  • [28] Synthesis and Surface Properties of a New Fluorinated Acrylic Diblock Copolymer via AGET ATRP
    Guo, Yanjuan
    Liu, Weiqu
    POLYMER SCIENCE SERIES B, 2016, 58 (03) : 313 - 320
  • [29] Preparation and properties of antibacterial fluorinated acrylic emulsion
    Chen, Zhanglian
    Wang, Qian
    Zhang, Zhaohui
    Lei, Huibin
    REACTIVE & FUNCTIONAL POLYMERS, 2021, 163
  • [30] The Chemical Composition of the Near-Surface Layer of Metal Substrates According to XPS Data and Its Effect on the Physical-Mechanical Properties of Acrylic Polymers
    Aslamazova, T. R.
    Grafov, O. D.
    Kotenev, V. A.
    PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2022, 58 (06) : 1141 - 1149
12345