Metal-ligand stability constants of Co (II), Ni (II) and Cu (II) metal ion complexes with N-(5-methyl-2-hydroxyacetophenone)-N'-(2-hydroxyacetophenone) ethylenediamine at 0.1 M ionic strength pH metrically

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作者
Maldhure, A.K. [1 ]
Agarkar, S.S. [1 ]
Taywade, R.K. [1 ]
Wankhade, R.S. [1 ]
机构
[1] Department of Chemistry, Arts, Commerce and Science College, Narsamma Campus, Kiran Nagar, Amravati, India
关键词
Metals - Ligands - Cobalt compounds - Copper compounds - Nickel compounds - Stability - Ionic strength;
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摘要
The interaction of Co(II), Ni(II) and Cu(II) metal ions with N-(5-methyl-2-hydroxyacetophenone)-N'-(2- hydroxyacetophenone) ethylenediamine have been studied at 0.1M ionic strength in 70% Dioxane-water mixture by Bjerrum method as adopted by Calvin and Wilson. It is observed that Co(II), Ni(II) and Cu(II) metal ions form 1:1 complexes with ligand (L). The data obtained were used to estimate and compare the values of proton-ligand stability constant (pK) and metal-ligand stability constant (logK), from estimated data (pK and log K).
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页码:3865 / 3868
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