Luminescent characteristics and energy transfer of a red-emitting YVO 4:Sm3+, Eu3+ phosphor

被引:0
作者
Zhang, Feng [1 ]
Zhang, Weifeng [1 ]
Zhang, Zhiya [2 ]
Huang, Yan [3 ]
Tao, Ye [3 ]
机构
[1] Key Lab of Photovoltaic Materials of Henan Province, School of Physics and Electronics, Henan University, Kaifeng 475001, China
[2] Department of Materials Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
[3] Laboratory of Beijing Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Samarium compounds - Phosphors - Energy transfer;
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摘要
Eu3+ and Sm3+ single-doped and co-doped YVO 4 phosphors have been synthesized and their photoluminescence properties in the VUV-VIS region were investigated. Under the excitation of 405 nm, the emission intensity of the optimal phosphor YVO4:Sm 3+0.05,Eu3+0.05 at 619 nm was largely enhanced compared to that of the sample without Sm3+, owing to the energy transfer from Sm3+ to Eu3+. The mechanism involved in this process has been explained and elucidated by an energy level diagram. While under the excitation of 147 nm, the emission intensity of YVO4:Sm3+0.05,Eu3+0.05 at 619 nm encounters a decreasing after the introducing of Sm3+ which is probably due to the competing of absorption energy of host between Sm 3+ and Eu3+. © 2013 Elsevier B.V.
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页码:160 / 164
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