A Reactive Molecular Dynamics Simulation of Thermal Aging Process of Oil-Paper Insulation and the Influence Mechanism of Moisture

被引：0

作者：

Li J. ^{[1
]}

Chen J. ^{[1
]}

Zhu M. ^{[1
]}

Song H. ^{[1
]}

Zhang H. ^{[2
]}

机构：

[1] College of Information and Control Engineering, China University of Petroleum (East China), Qingdao

[2] College of Chemical Engineering, China University of Petroleum (East China), Qingdao

来源：

Diangong Jishu Xuebao/Transactions of China Electrotechnical Society | 2020年 / 35卷 / 09期

关键词：

Moisture; Oil-paper composite insulation; Reaction force field; Reactive molecular dynamics; Thermal aging;

D O I：

10.19595/j.cnki.1000-6753.tces.190315

中图分类号：

学科分类号：

摘要：

H High temperature and moisture are the main causes of deterioration of oil-paper insulation in transformer, which is important to analyze the degradation mechanism. Molecular models for oil-paper composite insulation were built, and thermal aging processes of insulation under different moisture contents were simulated by using reaction force field (ReaxFF). The amount of reactants and products in the aging process was monitored, and then the main reaction path of oil-paper insulation aging and interaction mechanism between oil-paper were obtained by isotope labeling method. The influence of moisture on thermal aging process of composite insulation was emphatically analyzed. The results indicate that main products of oil-paper aging are H2, C2H4, CH4, H2O, CH2OHCHO, HCOOH, CO2 and CO. Hydrogen bonds are easy to form between water and cellobiose molecules under high temperature, destroying the structure of cellobiose. Besides, water and acid molecules generated by the decomposition of cellobiose can promotes deterioration of insulating oil. Oil and paper insulation aging promote each other under the influence of H+, which can accelerate composite insulation aging. © 2020, Electrical Technology Press Co. Ltd. All right reserved.

引用

页码：1999 / 2005

页数：6

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