Synergistic atmospheric influence on the co-pyrolysis of antibiotic sludge and waste bicycle tires: Optimal drivers, products, and pathways

Effective management of antibiotic sludge (AS) is essential for disease prevention. This study investigated the copyrolysis of AS with polyurethane (PU) and rubber tires (RT), focusing on its key drivers, synergies, resulting products, and atmospheric (N2 versus CO2) dependency. Composite pyrolysis index indicated superior copyrolysis properties of AS with PU or RT in the CO2 atmosphere compared with those in the N2 atmosphere. The strongest synergistic effect occurred at an optimal ratio of 75 % AS to 25 % PU (AP31) or 25 % RT (AR31), regardless of the atmosphere. Real-time gas analysis revealed greater product diversity in N2 than in CO2, with AS-derived products predominating. The co-pyrolysis altered AS nitrogen groups, promoting pyrrolic-N and pyridinic-N formation, and accelerated organic sulfur decomposition. Experimental results combined with univariate and multivariate joint optimizations identified the co-pyrolysis pathways of AP31 (650 - 800 degrees C) and AR31 (600 - 800 degrees C), respectively, in the CO2 atmosphere as synergistically optimal for maximizing resource recovery while minimizing waste and pollutant generation. This study provides actionable insights into the synergistic co-pyrolysis of AS with PU or RT, facilitating optimized gas emissions, energy recovery, and resource reuse.